EFFECT OF REACTOR WALL TEMPERATURE ON BENZENE OXIDATION IN A BARRIER DISCHARGE

Author:

Leshchik A. V.,Ochered'ko Andrey N.,Kudryashov S. V.,Ryabov A. Yu.,Petrenko T. V.

Abstract

Results of the experimental studies of the effect of reactor wall temperature on the direct oxidation of benzene to phenol in a barrier discharge reactor are presented. The main products of oxidation are phenol, hydroquinone, and pyrocatechol. It has been found out that the content of phenol and pyrocatechol in the mixture remains practically unchanged upon the air or oxygen benzene oxidation. An increase in the reactor wall temperature in the case of air oxidation of benzene results in a decrease in the hydroquinone content in the mixture of reaction products, while in the case of oxygen oxidation of benzene an increase in the hydroquinone content is observed. An increase in the reactor wall temperature also promotes an increase in the mass of liquid and solid reaction products, while the elemental composition of the precipitate remains unchanged.

Publisher

Begell House

Subject

Physical and Theoretical Chemistry,Spectroscopy,General Engineering,Energy Engineering and Power Technology,Condensed Matter Physics,General Materials Science

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