PREPARATION AND THERMOELECTRIC PROPERTIES OF rGO/Bi2Te3/PEDOT:PSS COMPOSITE BLOCK

Author:

Li Fanguo,Li Junping,Zhang Zhang,Yan Peimei,Zhang Fengjiao,Liu Hai

Abstract

Reduced graphene oxide/bismuth telluride (rGO/Bi<sub>2</sub>Te<sub>3</sub>) bulk composite materials containing the poreforming agent, sodium chloride (NaCl), were prepared by a hot-pressing sintering method after mixing rGO/Bi<sub>2</sub>Te<sub>3</sub> nanopowders with NaCl powders. Three-dimensional connected holes formed in the bulk composite materials after removing the NaCl pore-forming agent. Next, rGO/Bi<sub>2</sub>Te<sub>3</sub>/poly(3,4-ethylen edioxythiophene):poly(styrene sulfonate (PEDOT:PSS) nanocomposite bulk materials were prepared by filling PEDOT:PSS into the as-prepared three-dimensional connected holes in the rGO/Bi<sub>2</sub>Te<sub>3</sub> bulk composite skeletons. The effects of the PEDOT:PSS filling procedure on the compositions and microstructures of the rGO/Bi<sub>2</sub>Te<sub>3</sub>/PEDOT:PSS nanocomposite bulk materials were studied. The influence of the contents of NaCl and measurement temperatures on the thermal electrical properties of the bulk composite materials was investigated. A power factor of 560 &mu;W/(m<sup>-1</sup>&#183;K<sup>-2</sup>) was obtained at 400 K for the rGO/Bi<sub>2</sub>Te<sub>3</sub>/PEDOT:PSS nanocomposite bulk materials.

Publisher

Begell House

Subject

Physical and Theoretical Chemistry,Spectroscopy,General Engineering,Energy Engineering and Power Technology,Condensed Matter Physics,General Materials Science

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