Texturing and Tetragonal Phase Stabilization of ALD HfxZr1-xO2 Using a Cyclical Deposition and Annealing Scheme

Author:

Tapily Kandabara,Consiglio Steven,Clark Robert D.,Vasić Relja,Bersch Eric,Jordan-Sweet Jean,Wells Ilyssa,Leusink Gert J.,Diebold Alain C.

Abstract

In order to enhance the dielectric properties of HfO2, the alloying of HfO2 with ZrO2 was studied. HfxZr1-xO2 films with different Hf:Zr ratios were deposited by atomic layer deposition (ALD) combined with a cyclical deposition and annealing scheme (termed DADA) in which an annealing was performed after every 20 ALD cycles. The impact of the ZrO2 addition on the structural properties of the ALD grown films was investigated by grazing incidence in-plane X-ray diffraction and pole figure measurement using synchrotron radiation as well as transmission electron microscopy and X-ray photoelectron spectroscopy. The HfxZr1-xO2 films with x=1 show the presence of monoclinic (-111) fiber texture. As the Zr content increases, stabilization of the tetragonal phase is observed. The pole figure measurements indicate the presence of tetragonal (111) fiber texture for the ALD HfxZr1-xO2 films with higher Zr content grown by DADA in contrast to random orientation in post deposition annealed films.

Publisher

The Electrochemical Society

Cited by 22 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3