Abstract
We report on a facile strategy towards fabrication and testing of tungsten oxide and gold nanoparticles decorated PEDOT-PSS ternary nanocomposite (PEDOT: PSS-WO2-Au) as a flexible electrode material for supercapacitor applications. The morphological and structural features of the bare PEDOT-PSS and PEDOT: PSS-WO2-Au ternary nanocomposites were analyzed through scanning electron microscopy and Fourier transforms infra-red spectroscopy, whereas the thermal stability of the samples was studied through theromogravimetric analysis. The presence of Au nanoparticles significantly enhances the room temperature conductivity from 3 S cm−1 for bare PEDOT-PSS to 1552 S cm−1 for the ternary composite. This ternary composite electrode displays superior electrochemical performance with a specific capacitance of 462 Fg−1 in comparison to 112 Fg−1 for bare PEDOT-PSS and 359.25 Fg−1 for PEDOT-PSS: WO2 composite. The nanocomposite electrode displays capacitance retention of ∼92% after 5000 cycles of operation. The investigated ternary electrode shows excellent flexibility without capacitance fading under bending and rolling conditions.
Publisher
The Electrochemical Society
Subject
Materials Chemistry,Electrochemistry,Surfaces, Coatings and Films,Condensed Matter Physics,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials
Cited by
5 articles.
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