Abstract
In this work, a facile and accurate method is reported for the delocalization of negative charge on fluorinated polymers to obtain high-performance single-ion conducting polymer electrolytes (SICPs) based on brush copolymers with simultaneous high ionic conductivity and tLi+. The poly(styrene sulfonate) (PSSA) single ion-conducting moieties were grafted-from C–F linkages to the fluorinated polymer’s backbone via the atom transfer radical polymerization method. The chemical structure characterization of the synthesized brush copolymers via 1H-NMR and thermal gravimetric analyses (TGA) confirmed 25% grafting of PSSA to the poly(vinylidene fluoride) backbone. In continue, the pristine and single-ion fluorinated polymer membranes with bi-continuous honeycomb-like morphology structures were prepared via the vapor-induced phase inversion (VIPS) method. After immersing in a liquid electrolyte, the prepared SICP demonstrated promising ionic conductivity (σ), t
Li+
, and electrochemical stability of 1.9 × 10−3 Scm−1, 0.82, and 5.2 V (vs Li+/Li), respectively. The assembled Li/SICP/LiMn2O4 half-cells revealed an improved discharge capacity of 168 mA hg−1 at 0.1C. The charge-discharge studies revealed that the ohmic-resistance and polarization resistance of fluorinated polymer electrolytes could be decreased by the effect of PSSA-grafted moieties. The results of this work confirmed the promising capability of these new SICPs for high-safety LIBs.
Publisher
The Electrochemical Society
Subject
Materials Chemistry,Electrochemistry,Surfaces, Coatings and Films,Condensed Matter Physics,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials
Cited by
2 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献