From Lab to Manufacturing Line: Guidelines for the Development and Upscaling of Aqueous Processed NMC622 Electrodes

Abstract

Lithium-ion batteries (LIBs) have facilitated the transition to a more sustainable energy model. Paradoxically, current high energy cathodes are industrially processed using organic solvents, which are deleterious for the environment. In this work, LiNi0.6Mn0.2Co0.2O2 (NMC622) high-energy cathode electrode was prepared at laboratory scale following a more environmentally friendly aqueous route. Several steps in the preparation of the electrodes (such as the drying temperature, drying air flux or pH buffering) were thoroughly optimized to enhance the quality of the water-processed electrodes. Afterwards, the recipe developed at laboratory scale was upscaled to a semi-industrial electrode coating line, to analyze the viability of the developed processing conditions into a realistic electrode manufacturing environment. The electrodes obtained were tested in full coin cells using graphite-based anodes as counter electrodes. Interestingly, the cycling performance of the cells based on water-processed electrodes was higher than that of organic-processed ones. It is evidenced that it is possible to manufacture electrodes for high energy density LIBs following environmentally friendly, cheaper, and industrially implementable electrode processing methods with no-penalty in the electrochemical performance.