Research Development on Spinel Lithium Manganese Oxides Cathode Materials for Lithium-Ion Batteries

Author:

Zhang Yanli,Zhang Wenjuan,Zhou Jiakun,Li Xiaoning,Zhou Wenzhang,Xie Yanting,Mao JingORCID,Dai KehuaORCID

Abstract

Spinel LiMn2O4 (LMO) is a cathode material that features 3D Li+ diffusion channels, and it offers a range of benefits including low cost, non-toxicity, environmental friendliness, high safety, and excellent rate performance. Consequently, it has become a popular cathode material for lithium-ion batteries, having gained practical application. However, the cycling performance of LMO is still limited by problems such as Jahn-Teller distortion and Mn dissolution. In recent years, researchers have proposed various preparation and modification methods to address these problems and achieve wider commercialization of LMO cathode materials. This paper introduces the spinel structure of LMO and its degradation mechanisms, listing several common methods for synthesizing LMO cathode materials and modification approaches aimed at improving cyclic stability.

Funder

the Energy Storage Materials and Processes Key Laboratory of Henan Province Open Fund

the Key Research and Development and Promotion of Special Projects

Publisher

The Electrochemical Society

Subject

Materials Chemistry,Electrochemistry,Surfaces, Coatings and Films,Condensed Matter Physics,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials

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