Communication—Mg2+/0 as a Reliable Reference Electrode for Molten Chloride Salts

Author:

Lhermitte Charles R.ORCID,Parker S. ScottORCID,Jackson J. MattORCID,Monreal Marisa J.ORCID

Abstract

In this report, we describe the use of the Mg2+/0 couple as a reference in molten MgCl2-NaCl. We demonstrate that this redox couple provides a robust and reliable reference potential over a range of melt temperatures (500 °C–675 °C). Finally, we demonstrate the construction of a simple molten magnesium reference electrode, for operation at temperatures greater than the melting point of magnesium (650 °C).

Funder

Laboratory Directed Research and Development

Publisher

The Electrochemical Society

Subject

Materials Chemistry,Electrochemistry,Surfaces, Coatings and Films,Condensed Matter Physics,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials

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