Abstract
UO2 is an important nuclear fuel, also has potentials in the field of functional materials. In this work, the electrochemical behavior of UO2
2+ in LiCl-KCl molten salt (500 °C) and the effects of reduction potential (−0.1 to −1.0 V) and uranyl concentration (0.5 wt% to 4.0 wt%) on morphology and grain size of electrolytic products were studied. The reduction potential was found playing a decisive role in the morphology of cathodic products. When the potential was ≤−0.4 V (vs Pt(II)/Pt), dendritic and cracked characteristic of the UO2 crystal appeared. The average current density had a positive correlation with the grain size of cathodic products, and it increased first and then decreased with the increase of overpotential, having a maximum at −0.6 V (vs Pt(II)/Pt). On the other hand, the uranyl concentration also had a positive correlation with the grain size of the cathodic product without changing the integrity of grain morphology. For the preparation of large and granular UO2 crystal, the reduction potential of −0.2to−0.3 V (vs Pt(II)/Pt), as well as the uranyl concentration of greater than 2.0 wt% were recommended, and UO2 crystal with average grain size greater than 500 μm and high uniformity could be finally obtained.
Funder
Frontier Science Key Program of the Chinese Academy of Sciences
Strategic Priority Research Program of the Chinese Academy of Sciences
Publisher
The Electrochemical Society
Subject
Materials Chemistry,Electrochemistry,Surfaces, Coatings and Films,Condensed Matter Physics,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials
Cited by
1 articles.
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