Abstract
In order to develop organic compounds for achieving highly efficient anticorrosion of mild steel in HCl solution, this study proposed to synthesize new dendritic molecules (DMs 1,2) containing double norfloxacin skeletons. Besides, the linear molecule (LM) carrying a single norfloxacin framework was also prepared as the reference. The chemical structures of the studied molecules were fully characterized by nuclear magnetic resonance spectroscopy (1D and 2D NMR spectroscopy,1H,13C,19F), mass spectroscopy (MS), Fourier-transform infrared spectroscopy (FT-IR). For this purpose, the adsorption of the studied molecules on mild steel was investigated by different means. Furthermore, the potential kinetic polarization and electrochemical impedance spectroscopy (EIS) were used to survey the anticorrosion of the studied molecules in HCl solution at 298 K. It is shown that theDMsdisplayed superior corrosion inhibition effect on mild steel over theLMin acid medium at 298 K (the maximal corrosion inhibition efficiency,LM, 87.80%,DM1, 96.00%,DM2, 96.26% at 0.015 mM). The anticorrosion and adsorption mechanisms of the studied molecules for mild steel were further understood by molecular modeling and adsorption isotherms.
Funder
National Natural Science Foundation of China
Publisher
The Electrochemical Society
Subject
Materials Chemistry,Electrochemistry,Surfaces, Coatings and Films,Condensed Matter Physics,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials
Cited by
1 articles.
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