Abstract
Lithium-ion (Li-ion) batteries have undergone a multitude of improvements and achieved a high level of technological maturity. To further optimise cell performance, an understanding of the failure mechanisms is important. Forty-eight state-of-the-art cylindrical cells in the 21700 format, suitable for electric vehicles, are studied at the beginning-of-life (BOL) and end-of-life (EOL) by X-ray computed tomography (X-ray CT) and image analysis. The results indicate that shifting current collecting tabs closer to the centre of the cell and including a mandrel is likely to supress the propagation of capacity depleting deformations. It is recommended that manufacturers also try to improve cell assembly processes to form a more uniformly circular jelly roll and use tapered electrodes to minimise the nucleation of deformations.
Funder
Faraday Institution
Royal Academy of Engineering
Publisher
The Electrochemical Society
Subject
Materials Chemistry,Electrochemistry,Surfaces, Coatings and Films,Condensed Matter Physics,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials