Abstract
We report on stabilization of Li–S cells with different types of composite sulfur cathodes using ethereal LiTFSI/LiNO3/DOL/DME electrolyte solutions containing a-priori 0.1 M Li2S8. These electrolyte solutions enable an improved cycling behavior for Li–S cells compared to Li2S8-free electrolyte solutions, thanks to the presence of LiSx species from the beginning of operation. We show that Li anodes cycled in Li∣S cells with solutions containing Li2S8 possess flatter and more uniform surface, higher dimensions of the surface structures in average and, as a result, a lower surface area. This surface morphology ensures a low rate of parasitic surface reactions of the electrolyte components on the Li anodes’ surface, slower depletion of the electrolyte solution in the cells and stabilization of the cells cycling. Besides, the presence of Li2S8 maintains a better integrity of composite sulfur/carbon/PVdF cathodes, ensuring a better electronic contact between the particles in the composite cathodes. We believe that we outline herein a logical approach for practical Li–S batteries, emphasizing high energy density, cost effectiveness and relatively simple production procedures.
Publisher
The Electrochemical Society
Subject
Materials Chemistry,Electrochemistry,Surfaces, Coatings and Films,Condensed Matter Physics,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials
Cited by
3 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献