Determination of the Dissociation Energy of Diatomic Molecules by KEMS (Knudsen Effusion Mass Spectrometry): Intragroup 14 and Group 11-Group 2 Molecules
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Published:2013-05-01
Issue:1
Volume:46
Page:99-111
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ISSN:1938-5862
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Container-title:ECS Transactions
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language:
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Short-container-title:ECS Trans.
Author:
Ciccioli A.,Gigli G.
Abstract
This contribution summarize our recent work devoted to detect and thermochemically characterise by KEMS experiments (Knudsen Effusion Mass Spectrometry) a number of diatomic gaseous molecules either never observed before or whose bond energy was unknown. The results obtained over the years for the intragroup 14 and the group 11-group 2 species are here collected and compared with quantum chemical calculations at the CCSD(T) level.
Publisher
The Electrochemical Society