Calendar Degradation and Self-Discharge Occurring During Short- and Long-Term Storage of NMC Based Lithium-Ion Batteries

Abstract

Idling periods are a major part of the Lithium-ion battery operation. Due to parasitic reactions, the battery capacity is decreasing and self-discharge occurs over time. Thus, in order to predict the battery lifetime and optimize its operation, it is required to capture this behavior. In this study, two different storage periods of 2 and 6 months were investigated and used to develop and validate models dedicated to reversible and irreversible capacity loss. It has been observed that while for the shorter storage period, the self-discharge rate does not change significantly, for the longer storage period it decreased during aging. Moreover, the degradation rates vary significantly for various time scales at low temperature, while at medium and high temperatures they are matching closely for 2- and 6-months periodic storage.