(Invited) Frequency Dispersion and Band Alignments in ZrO2/n-GaAs MOS Capacitor
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Published:2014-03-24
Issue:2
Volume:61
Page:125-132
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ISSN:1938-5862
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Container-title:ECS Transactions
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language:
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Short-container-title:ECS Trans.
Author:
Konda R B,White C,Thomas D,Yang Q,Sahu D,Pradhan Aswini K
Abstract
The interfacial characteristics and band alignments of high-k ZrO2 on n-GaAs have been investigated by experimentally and density functional theory. We have demonstrated that the frequency dispersion due to interface traps in capacitance-voltage characteristics of ZrO2/GaAs interface was significantly reduced through self-cleaning by trimethylalumina. The experimental valence band offset of 2.10 eV from X-ray photoelectron spectroscopy is found to be lower than that of the calculated value of 3.02 eV. The calculated conduction band offset is 1.21 eV compared to the experimental value of 1.38 eV confirms significant reduction of interface traps due to the Fermi-level pinning minimizing the band misalignment.
Publisher
The Electrochemical Society