An XAFS Study of Nickel Chloride in the Ionic Liquid 1-Ethyl-3-Methyl Imidazolium Chloride/ Aluminum Chloride-Reference-Cited by-同舟云学术

An XAFS Study of Nickel Chloride in the Ionic Liquid 1-Ethyl-3-Methyl Imidazolium Chloride/ Aluminum Chloride

Published:2008-04-21 Issue:23 Volume:11 Page:29-36
ISSN:1938-5862
Container-title:ECS Transactions
language:
Short-container-title:ECS Trans.

Author:

Roeper Donald,Cheek Graham T.,Pandya Kumi,O'Grady William

Abstract

Nickel chloride was studied with cyclic voltammetry and X-ray absorption spectroscopy in acidic and basic aluminum chloride/1-ethyl-3-methyl imidazolium chloride (EMIC) ionic liquids. Acidic melts display metal stripping peaks which are not observed in the basic melt. EXAFS analysis shows that the nickel is tetrahedrally coordinated with chloride ions in the basic solution. In the acidic solution the nickel is coordinated by six chloride ions that are also associated with aluminum ions.

Publisher

The Electrochemical Society

Link

https://iopscience.iop.org/article/10.1149/1.2910230/pdf

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