Microelements in the Late Pleistocene ice wedges of Seyakha yedoma, east of Yamal Peninsula

Abstract

The subject of this research is the composition of micro- and macro- rare earth elements in the Late Pleistocene syngenetic ice wedges of the Seyakha yedoma, explored in the outcrop of the Gulf of Ob in the east of Yamal Peninsula (70°9'27.88 "N, 72° 34'8.31" E), north of the Western Siberia. The All-Russian Scientific-research Institution of Mineral Resources after named N.M. Fedorovsky examined the composition of chemical elements in the ice wedges using the methods of atomic-emission spectrometry and mass spectrometry with inductively linked plasma (spectrometers Elan-6100, Optima-4300DV, Perkin-Elmer, Polyvac E-1000, Rank Hilger). The following conclusions were made: 1) Ice wedges of the Seyakha yedoma are rich in macro - and microelements was recorded, which exceeds such in ice wedges of Yakutia by 8-10 times. The high composition of microelements indicates the role of aerosol and soil particles in the formation of chemical composition of ice. The differences between the ice of Yamal and Northeastern Yakutia also testify that the chemical composition reflects the involvement of marine aerosols in ice formation. 2) Rare-earth elements accumulate in the ice of Seyakha yedoma. The composition of all rare-earth elements exceeds the Clarke number in river waters by 69 (Tm ) – 382 (Y) times. 3) Variability of microelement composition within the ice wedge is insignificant, which implies that the water of the polluted with dust and aerosols spring-summer snow is filtered through the entire snow layer and is partially cleaned prior to getting into the ice-break in the ground under the snow.