Regularities of the radical copolymerization of dodecyl (meth) acrylate and a new cationic monomer N-(dibutylaminomethyl) methacrylamide

Author:

Arifullin I. R.1,Shirshin K. V.2,Kazantsev O. A.1,Savinova M. V.1,Ryabova T. A.1

Affiliation:

1. Nizhny Novgorod State Technical University

2. Nizhny Novgorod State Technical University; V.A. Kargin Polymer Chemistry and Technology Research Institute

Abstract

The regularities of radical copolymerization of dodecyl methacrylate (DMA) or dodecyl acrylate (DA) with a new cationic monomer - N-(dibutylaminomethyl) methacrylamide (DBAMMA) in toluene solutions were determined. The copolymers formed at low conversions in the DMA-DBAMMA system are enriched in ether units, and in the DA-DBAMMA system - in aminoamide units. The relative activities of comonomers determined by the Feineman-Ross and Kehlen-Tudosh methods in the first case were 1.56-1.60 (DMA) and 0.87-0.89 (DBAMMA), in the second case - 0.53-0.64 (DA) and 0.80-0.90 (DBAMMA).

Publisher

Publishing House Plastic Ltd

Subject

Polymers and Plastics,Chemical Engineering (miscellaneous)

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