Abstract
The ground state electronic and fluorescence spectra of unsubstituted copper(II) phthalocyanine (CuPc) has been studied in the presence of bovine serum albumin (BSA) in water as solvent. The effect of sodium dodecyl sulfate (SDS) on the solution properties of CuPc: BSA bioconjugate has also been investigated. FT-IR, UV-Vis, and fluorescence analysis have been carried to evaluate the BSA:CuPc bioconjugation. The optimum bioconjugate ratio of BSA:CuPc has been studied via UV-Vis and fluorescence spectral techniques. The collaborative effect of SDS with BSA on the aggregation of CuPc suspension has also been studied in terms of UV-Vis, fluorescence, and FT–IR analysis.
Publisher
Kocaeli Journal of Science and Engineering
Subject
General Earth and Planetary Sciences,General Environmental Science
Reference62 articles.
1. [1] Hanack M., Heckmann H., Polley R., 1998. Schaumann E, editor. Houben-Weyl methods of organic chemistry. 4th ed., vol. E 9d. Phthalocyanine and Related Compounds. Stuttgart (Germany): Georg Thieme Verlag. p. 717.
2. [2] Claessens C. G., Hahn U., Torres T., 2008. Phthalocyanines: From Outstanding Electronic Properties to Emerging Application, Chemical Record, 8(2), pp. 75-97.
3. [3] Dumoulin F., Durmuş M., Ahsen V., Nyokong T., 2010. Synthetic Pathways to Water-soluble Phthalocyanines and Close Analogs, Coordination Chemistry Reviews, 254(23–24), pp. 2792-2847.
4. [4] De la Torre G., Vázquez P., Agulló-López, Torres T., 2004. Role of Structural Factors in the Nonlinear Optical Properties of Phthalocyanines and Related Compounds, Chemical Reviews, 104(9), pp. 3723–3750.
5. [5] Zorlu Y., Dumoulin F., Bouchu D., Ahsen V., Lafont D., 2010. Monoglycoconjugated Water-Soluble Phthalocyanines. Design and Synthesis of Potential Selectively Targeting PDT Photosensitisers, Tetrahedron Letters, 51(50), pp. 6615-6618.