Affiliation:
1. ESKISEHIR OSMANGAZI UNIVERSITY
2. eskişehir osmangazi üniversitesi
Abstract
In this study (4-(3-iodobenzo[b]thiophen-2-yl)-N,N-dimethyllaniline (4), Sonagashira Coupling Reaction was synthesized using Electrophilic Cyclization Reactions. Then, the anode catalyst performance for glucose electrooxidation was investigated. The electrocatalytic activities of the organic catalyst were investigated by CV, CA and EIS measurements in 1 M KOH + 0.5 M C6H12O6 solution. Interestingly, electrochemical depositing on organic catalyst by Pd metal increased the specific activity, and it was calculated as 0.61 mA/cm2 Consequently, Pd@4 catalyst will be used as an electrocatalyst with high specific and stability and low charge transfer activity.
Publisher
Kyrgyz-Turkish Manas University
Reference21 articles.
1. [1]. Erdem, K.O.Ç. and Kadir, K., 2015. Enerji Kaynakları–Yenilenebilir Enerji Durumu. Mühendis ve Makina, 56(668), pp.36-47.
2. [2]. Oğulata, R. 2007. “Potential of Renewable Energies in Turkey,” Energy Engineering, vol. 133 (1), p. 63-68.
3. [3]. Park, M., Lee, T. and Kim, B.S., 2013. Covalent functionalization based heteroatom doped graphene nanosheet as a metal-free electrocatalyst for oxygen reduction reaction. Nanoscale, 5(24), pp.12255-12260.
4. [4]. Clarke, T.M. and Durrant, J.R., 2010. Charge photogeneration in organic solar cells. Chemical reviews, 110(11), pp.6736-6767.
5. [5]. Kivrak, H., Can, M., Duru, H. and Sahin, O., 2014. Methanol electrooxidation study on mesoporous silica supported Pt–Co direct methanol fuel cell anode. International Journal of Chemical Reactor Engineering, 12(1), pp.369-375.