Catalytic Properties of Electroless Nickel-Based Coatings Modified by the Magnetic Field

Author:

Kołczyk-Siedlecka K.1ORCID,Kutyła D.1ORCID,Skibińska K.1ORCID,Jędraczka A.1ORCID,Żabiński P.1ORCID

Affiliation:

1. AGH University of Krakow, Faculty of Non-Ferrous Metals, Al. Mickiewicza 30, 30-059 Krakow, Poland

Abstract

In this work the nickel-based coatings were obtained by electroless catalytic deposition on light-hardened resins dedicated for 3D printing by SLA method. The effect of external magnetic field application on the properties of nickel-based coatings was determined. During metallization, the magnetic field was applied to the sample’s surface with different orientations. Due to the magnetic properties of metallic ions, the influence of the magnetic field on coatings properties is expected. The coatings were analyzed by Energy-dispersive X-ray spectroscopy (ED S) the X-Ray diffraction (XRD ) methods, and surface morphology was observed by scanning electron microscopy (SEM). The catalytic properties in a hydrogen evolution reaction (HER ) were measured by electrochemical method in 1 M NaOH solution. The best catalytic activity has been observed in the case of the ternary Ni-Fe-P alloy deposited under a parallel magnetic field. The primary outcome of the presented research is to produce elements based on 3D printing from resins, which can then be metallized and used for highly-active materials deposited on complex 3D models. Furthermore, these elements can be used as low-cost, highly-developed sensors and catalysts for various chemical processes.

Publisher

Polish Academy of Sciences Chancellery

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