Argentopolybasite, Ag16Sb2S11, a new member of the polybasite group

Abstract

AbstractThe new mineral argentopolybasite, ideally Ag16Sb2S11, was found at the Kremnica Au–Ag epithermal deposit, Žiar nad Hronom Co., Banská Bystrica Region, Slovakia (type locality), Šibeničný vrch near Nová Baňa, Žarnovica Co., Banská Bystrica Region, Slovakia (cotype locality) and the Arykevaam epithermal Au–Ag deposit, Anadyr’ District, Chukotka Autonomous Okrug, Russian Federation (cotype locality). At the Kremnica deposit argentopolybasite was found as discrete, well-developed (pseudo)hexagonal tabular crystals up to 4 mm in size or as complex crystalline aggregates and groups up to 5 mm in size in cavities of quartz. It is associated with pyrargyrite, polybasite, stephanite, miargyrite, rozhdestvenskayaite-(Zn), argentotetrahedrite-(Zn), naumannite, gold and pyrite. Argentopolybasite is dark grey to black, with a black streak and metallic to opaque lustre. The Mohs hardness is ~3. It is brittle with no observable cleavage and with a conchoidal fracture. The calculated density is 6.403 g⋅cm–3. In reflected light, argentopolybasite is grey, with no observable bireflectance and very weak pleochroism. It shows moderate anisotropy in crossed polarisers with weak greenish and green–blue tints. The reflectance values for wavelengths recommended by the Commission on Ore Mineralogy of the IMA are (Rmin/Rmax, %): 30.3/31.0 (470 nm), 28.8/29.3 (546 nm), 28.1/28.6 (589 nm) and 27.4/27.8 (650 nm). The empirical formulae (based on 29 apfu) are, Kremnica: (Ag15.94Cu0.18)Σ16.12(Sb1.40As0.61)Σ2.01(S10.60Se0.25Cl0.03)Σ10.88, Nová Baňa: Ag16.30(Sb1.74As0.22)Σ1.96(S10.69Cl0.04)Σ10.73 and Arykevaam: (Ag15.54Cu0.38)Σ15.92(Sb1.56As0.51)Σ2.07S11.01. The ideal end-member formula for argentopolybasite is Ag16Sb2S11. Argentopolybasite is trigonal, space group P321, a = 15.0646(5) Å, c = 12.2552(5) Å, V = 2408.61(15) Å3 and Z = 2. The seven strongest powder X-ray diffraction lines are [dobs in Å, (I), hkl]: 12.169, (40), 001; 3.162, (100), 041; 3.045, (54), 004; 2.881, (45), 042; and 2.4256, (28), 421. The crystal structure of argentopolybasite from Kremnica, refined to Robs = 0.0741 for 2804 observed reflections, confirmed that the atomic arrangement is isotypic to that of the other members of the polybasite group and it is isostructural with argentopearceite.