Author:
Borges Roger,Dutra Lívia Macedo,Barison Andersson,Wypych Fernando
Abstract
AbstractThe milling process in the solid-state 2:1 clay minerals, montmorillonite and talc, which have different cation exchange capacities, is reported here. Several instrumental techniques were used to monitor systematically the products formed. The dehydroxylation/amorphization of the montmorillonite and talc structures occurs within 3 and 6 h of milling, respectively. Electron paramagnetic resonance spectra indicated that structural Mn2+ was oxidized more quickly in the montmorillonite structure than in talc, while the paramagnetic defects increased during milling. Nuclear magnetic resonance was also used to monitor the environmental changes for Si and Al during milling.
Subject
Geochemistry and Petrology
Cited by
24 articles.
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