Raman spectroscopy of gaseous inclusions in EDML ice core: first results – microbubbles

Abstract

AbstractMeasurements of N2/O2 ratios inside individual air bubbles at various depths in the EDML (Antarctic) ice core are presented here. The small bubbles (diameter less than ~200 µm) in deeper ice are significantly enriched in O2 compared to the larger bubbles. The N2/O2 ratios show a systematic dependence on bubble size which is not the case for bubbles in shallower ice. This is interpreted as an effect of pressure relaxation during storage of the cores.