Synthesis of the BEAC4ND4 Ionophore from p-t-Butylcalix[4]arene Carboxylic Acid-Reference-Cited by-同舟云学术

Synthesis of the BEAC4ND4 Ionophore from p-t-Butylcalix[4]arene Carboxylic Acid

Published:2020-12-29 Issue:12 Volume:23 Page:424-431
ISSN:2597-9914
Container-title:Jurnal Kimia Sains dan Aplikasi
language:
Short-container-title:J. Kim. Sains Apl.

Author:

Dali Nasriadi¹^ORCID,Dali Arniah²^ORCID,Dali Seniwati³,Amalia Hilda Ayu Melvi⁴

Affiliation:

1. Department of Chemistry, Halu Oleo University Kendari

2. Department of Chemistry Education, Faculty of Teacher Training and Education, Halu Oleo University Kendari

3. Department of Chemistry, Faculty of Mathematics and Natural Sciences, Hasanuddin University Makassar

4. Study Program of Tadris Biology, Faculty of Tarbiyah and Teacher Training, Institut Agama Islam Negeri IAIN Kendari Kendari

Abstract

The BEAC4ND4 ionophore has been successfully synthesized from p-t-butylcalix[4]arene carboxylic acid. The BEAC4ND4 ionophore was obtained in two steps of the synthesis reaction. The first step is the chlorination reaction of p-t-butylcalix[4]arene carboxylic acid with thionyl chloride in dry benzene solvent. The chlorination reaction product is p-t-butylcalix[4]arene acyl chloride in the form of the light brown viscous liquid with a yield of 78.25% and TLC (SiO2, CH3OH: CH2Cl2 = 1: 1 v/v, Rf = 0.65). The second step is the amidation reaction of ethyl 2-aminoacetate with p-t-butylcalix[4]arene acyl chloride in dry tetrahydrofuran solvent. The product of the amidation reaction is p-t-butylcalix[4]arene ethylesteramide or the BEAC4ND4 ionophore in the form of a white solid with the yield of 75.22%, a melting point of 314-316°C, and TLC (SiO2, CH3OH: CH2Cl2 = 1: 1 v/v, Rf = 0.75).

Funder

Halu Oleo University

Publisher

Institute of Research and Community Services Diponegoro University (LPPM UNDIP)

Reference9 articles.

1. Cation complexation by chemically modified calixarenes. Part 10. Thioamide derivatives of p-tert-butylcalix[4]-, [5]- and [6]-arenes with selectivity for copper, silver, cadmium and lead. X-Ray molecular structures of calix[4]arene thioamide–lead(II) and calix[4]arene amide–copper(II) complexes

2. Transduction of selective recognition of heavy metal ions by chemically modified field effect transistors (CHEMFETs)

3. SYNTHESIS OF TETRA-p-PROPENYLTETRAESTERCALIX[4]ARENE AND TETRA-p-PROPENYLTETRACARBOXYLICACIDCALIX[4]ARENE FROM p-t-BUTYLPHENOL

4. Calixarenes as sensor materials for recognition and separation of metal ions

5. Synthesis of the BCAC4ND2 Ionophore from p-t-Butylcalix[4]arene Ethylester

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synthesis of the BETAC4ND5 ionophore from p-t-butylcalix[4]arene ethylesteramide;THE 9TH INTERNATIONAL CONFERENCE OF THE INDONESIAN CHEMICAL SOCIETY ICICS 2021: Toward a Meaningful Society;2022