Affiliation:
1. Department of Geology, Colgate University, Hamilton, New York 13346, U.S.A.
2. † Special collection papers can be found online at http://www.minsocam.org/MSA/AmMin/special-collections.html.
Abstract
Abstract
Crushed ore in Adirondack wollastonite mines (New York) shows textural evidence for wollastonite dissolution and cementation by calcite and opal. The reaction CaSiO3 + CO2 = CaCO3 + SiO2 is a model reaction for silicate weathering and carbonation that has not been characterized in the field until now (outside of controlled experiments). Cemented samples from the Lewis and Fox Knoll mines contain up to 3% and 6% calcite, respectively, and contain modern 14C. Carbon isotope ratios have an organic signature at both mines but more strongly at Lewis (δ13C from –9‰ to –29‰ VPDB), which, along with observed filamentous biofilms, supports a microbial role in mineralization.
Differences are seen between wollastonite weathering in these mines vs. wollastonite weathering in lab experiments and field studies of carbonate formation in other rock types. Grains surrounded by reaction products reach complete dissolution here, indicating that passivation by jacketing is not important at the field sites. Also, dissolved ions do not all form in situ reaction products, suggesting that solutes are leaving the system. A key finding of this study is the strong organic δ13C signature of calcite cements at the Lewis mine, which also show higher calcite content per years of exposure compared to cements at the Fox Knoll mine. Although microbial fractionation complicates isotopic assessment of atmospheric CO2 sequestration, our findings suggest sequestration rates are enhanced by geomicrobiological activity.
Publisher
Mineralogical Society of America
Subject
Geochemistry and Petrology,Geophysics
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