The Electrical Double Layer Parameters for the Group 4 Metal Oxide/Electrolyte System-Reference-Cited by-同舟云学术

The Electrical Double Layer Parameters for the Group 4 Metal Oxide/Electrolyte System

Published:2000-03 Issue:2 Volume:18 Page:117-134
ISSN:0263-6174
Container-title:Adsorption Science & Technology
language:en
Short-container-title:Adsorption Science & Technology

Author:

Janusz Władysław¹

Affiliation:

1. Department of Radiochemistry and Colloid Chemistry, Maria Curie-Sklodowska University, pl. Marii Curie-Sklodowskiej 3, 20-031 Lublin, Poland

Abstract

The electrical double layer parameters for Group 4 metal oxide/NaCl solution systems are presented. The surface charge density and the adsorption of background electrolyte ions as a function of the pH of the solution and the concentration of the electrolyte for the ZrO2 and HfO2 systems are presented. Through the use of numerical optimization, the apparent reaction constants for the surface hydroxy group were calculated. The characteristic points of the electrical double layer and the ionization and complexation constants of the surface hydroxy groups are compared with those predicted semi-theoretically.

Publisher

Hindawi Limited

Subject

Surfaces and Interfaces,General Chemical Engineering,General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.1260/0263617001493332

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