Ion-Exchange and Adsorption Properties of Titania Gels Prepared from Titanous Chloride and Hydrogen Peroxide

Author:

Yacoub Nahed1,Ramadan Adham R.1,Ragai Jehane1

Affiliation:

1. Department of Chemistry, The American University in Cairo, 113 Kasr El Aini Street, P.O. Box 2511, Cairo, Egypt

Abstract

A study was carried out of the uptake of Cu2+, Ni2+, Co2+ and Ca2+ cations by hydrous titanium oxides prepared at different pH values using titanous chloride as the starting material and hydrogen peroxide as the oxidizing agent. Characterization of the oxides was carried out by nitrogen adsorption and infrared studies. The oxides were found to be amphoteric in nature and exhibited an isoelectric point of 6.6. An attempt was made to elucidate the mechanism of cation uptake which does not entail a simple ion-exchange mechanism.

Publisher

Hindawi Limited

Subject

Surfaces and Interfaces,General Chemical Engineering,General Chemistry

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