Sorption of Metal Ions on a Mixed Oxide [0.5 M SiO2:0.5 M Fe(OH)3]

Abstract

The sorption of Zn2+, Ni2+, Cd2+, Ca2+ and Mg2+ ions on to a mixed oxide of iron and silicon was found to increase with increasing temperature, concentration and pH of the system. The selectivity of this mixed oxide was Cd2+ ≥ Zn2+ ≥ Ni2+ > Ca2+ > Mg2+, indicating that the mixed oxide was more selective as an exchanger towards Cd2+ ions relative to its components, SiO2 and Fe(OH)3. The sorption data fitted the linear forms of the Kurbatov and Langmuir adsorption equations. The sorption of metal cations was accompanied by the release of H+ ions to the bulk phase. On average 1 mol H+ was released for every cation sorbed. The values of the binding constants were used to estimate the apparent thermodynamic parameters, ΔH and ΔS. The phenomenon of enthalpy/entropy compensation showed that the adsorption of metal ions by the mixed oxide occurred typically through a cation-exchange mechanism.