Adsorption of Toxic Metal Ions onto Silica with Covalently Bound 8-Hydroxyquinoline

Author:

Yanovska E.S.1,Glushchenko O.V.1,Karmanov V.I.1,Kichkiruk O.Yu.2,Tertykh V.A.3

Affiliation:

1. Chemistry Department of Kiev National Taras Shevchenko University, Volodymyrska Str., 64, 01033 Kiev-33, Ukraine

2. I. Franko State University, Pushkin Str., 42, 10008 Zhitomir, Ukraine

3. Institute of Surface Chemistry of National Academy of Sciences of Ukraine, Gen. Naumov Str., 17, 03164 Kiev-164, Ukraine

Abstract

8-Hydroxyquinoline covalently bound to silica via a one-stage Mannich reaction was used as an adsorbent for the pre-concentration of Pb(II), Cd(II), Zn(II) and Mo(VI) ions from aqueous solutions in the dynamic mode following determination of their concentrations by X-ray fluorescence methods. The adsorption of Pb(II), Cd(II), Zn(II) and Mo(VI) ions was studied from individual and complex multi-component solutions of both natural and technogenic origins. Peculiarities associated with the simultaneous X-ray fluorescence determination of mixtures of toxic metal ions in a solid matrix are discussed.

Publisher

Hindawi Limited

Subject

Surfaces and Interfaces,General Chemical Engineering,General Chemistry

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