Comparing many-body approaches against the helium atom exact solution

Author:

Li Jing12,Drummond N. D.3,Schuck Peter145,Olevano Valerio612

Affiliation:

1. Grenoble Alpes University

2. Institut Néel

3. Lancaster University

4. Institut National de Physique Nucléaire et de Physique des Particules

5. Laboratoire de Physique et Modélisation des Milieux Condensés

6. European Theoretical Spectroscopy Facility

Abstract

Over time, many different theories and approaches have been developed to tackle the many-body problem in quantum chemistry, condensed-matter physics, and nuclear physics. Here we use the helium atom, a real system rather than a model, and we use the exact solution of its Schrödinger equation as a benchmark for comparison between methods. We present new results beyond the random-phase approximation (RPA) from a renormalized RPA (r-RPA) in the framework of the self-consistent RPA (SCRPA) originally developed in nuclear physics, and compare them with various other approaches like configuration interaction (CI), quantum Monte Carlo (QMC), time-dependent density-functional theory (TDDFT), and the Bethe-Salpeter equation on top of the \boldsymbol{GW}𝐆𝐖 approximation. Most of the calculations are consistently done on the same footing, e.g. using the same basis set, in an effort for a most faithful comparison between methods.

Publisher

Stichting SciPost

Subject

General Physics and Astronomy

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