Preparation and Characterization of Superabsorbent Polymer (SAP) by Graft Polymerization of Carboxymethyl Cellulose

Author:

Nazmul Islam A.B.M.1,Anisul Islam Md.2

Affiliation:

1. Daffodil International University

2. Rajshahi University

Abstract

The synthesis of superabsorbent polymer with Carboxymethyl cellulose using ceric ammonium nitrate (CAN) initiated acrylamide (AA) monomer through a solution based graft copolymerization has been conducted. The characterizing studies were performed using Fourier transform infrared (FTIR) spectroscopy, Atomic force microscopy (AFM) and swelling studies. FTIR spectra established crosslinked polymeric network structure of hydrogels through graft copolymerization reaction between CMC and acrylamide indicating incorporation of acrylamide monomer resulting the formation of carboxamide group (>C=O). AFM showed the surface morphology or properties of superabsorbent. The hydrophilic properties of the superabsorbent were identified by the swelling percentage or degree of swelling.

Publisher

AOA Academic Open Access Ltd.

Subject

Psychiatry and Mental health,Neuropsychology and Physiological Psychology

Reference14 articles.

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2. K. Kabiri, Synthesis of fast-swelling superabsorbent hydrogels: effect of crosslinker type and concentration on porosity and absorption rate, European Polymer Journal. 39 (2003) 1341–1348.

3. F.L. Buchholz, A.T. Graham, Modern Superabsorbent Polymer Technology, Elsevier, Amsterdam, (1997).

4. L.B. Peppas, R.S. Harland, Absorbent Polymer Technology, Elsevier, Amsterdam, (1990).

5. A. S. Hoffman, J.C. Salamone, Polymeric Materials Encyclopedia; CRC Press, Boca Raton, FL, (1996).

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