Interpretation of Valence Band X-Ray Spectra

Abstract

X -ray spectra arising from the valence bands of solids are useful for basic studies of the electronic structure of most materials and for practical measurements of unknowns to obtain information on local atomic structure and material properties as well as chemical composition. Understanding the characteristics of valence band spectra is prerequisite to their fullest use. One-electron and many-body aspects of the x-ray emission process, and the effects of experimental conditions, must be understood and are reviewed. Interpretation of spectral features and determination of electronic structure are complementary parts of one procedure which is based on the use of bonding theory. The various band and bond theories which are finding use for spectral interpretation are briefly reviewed. Calculation of the electronic structure of aluminum metal and quartz, and interpretation of their x-ray spectra, are examples which illustrate basic work with valence band spectra.