Advantages of Using Microbial Technology over Traditional Chemical Technology in Removal of Black Crusts from Stone Surfaces of Historical Monuments

Author:

Cappitelli Francesca1,Toniolo Lucia2,Sansonetti Antonio3,Gulotta Davide2,Ranalli Giancarlo4,Zanardini Elisabetta5,Sorlini Claudia1

Affiliation:

1. Dipartimento di Scienze e Tecnologie Alimentari e Microbiologiche, Università degli Studi di Milano, Milan

2. Dipartimento DCMIC Politecnico di Milano, Milan

3. CNR Istituto per la Conservazione e Valorizzazione dei Beni Culturali, Milan

4. Dipartimento di Scienze e Tecnologie Agro-Alimentari, Ambientali e Microbiologiche, Università degli Studi del Molise, Campobasso

5. Dipartimento di Scienze Chimiche e Ambientali, Università dell'Insubria, Como, Italy

Abstract

ABSTRACT This study compares two cleaning methods, one involving an ammonium carbonate-EDTA mixture and the other involving the sulfate-reducing bacterium Desulfovibrio vulgaris subsp. vulgaris ATCC 29579, for the removal of black crust (containing gypsum) on marble of the Milan Cathedral (Italy). In contrast to the chemical cleaning method, the biological procedure resulted in more homogeneous removal of the surface deposits and preserved the patina noble under the black crust. Whereas both of the treatments converted gypsum to calcite, allowing consolidation, the chemical treatment also formed undesirable sodium sulfate.

Publisher

American Society for Microbiology

Subject

Ecology,Applied Microbiology and Biotechnology,Food Science,Biotechnology

Reference24 articles.

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2. Atlas, R. M., A. N. Chowdhury, and L. K. Gauri. 1988. Microbial calcification of gypsum-rock and sulfated marble. Stud. Conserv.33:149-153.

3. Code of practice for cleaning and surface repair of buildings. Part 1. Cleaning of natural stones brick terracotta and concrete 2000

4. Improved Methodology for Bioremoval of Black Crusts on Historical Stone Artworks by Use of Sulfate-Reducing Bacteria

5. Castanier, S., G. Le Métayer-Levrel, G. Orial, J. F. Loubière, and J. P. Perthuisot. 2000. Bacterial carbonatogenesis and applications to preservation and restoration of historic property, p. 201-216. In O. Ciferri, P. Tiano, and G. Mastromei (ed.), Of microbes and art: the role of microbial communities in the degradation and protection of cultural heritage. Plenum, New York, NY.

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