Novel Allylic Oxidation of α-Cedrene to sec -Cedrenol by a Rhodococcus Strain-Reference-Cited by-同舟云学术

Novel Allylic Oxidation of α-Cedrene to sec -Cedrenol by a Rhodococcus Strain

Published:1993-05 Issue:5 Volume:59 Page:1336-1341
ISSN:0099-2240
Container-title:Applied and Environmental Microbiology
language:en
Short-container-title:Appl Environ Microbiol

Author:

Takigawa Hirofumi¹,Kubota Hiromi¹,Sonohara Hiroshi¹,Okuda Mitsuyoshi¹,Tanaka Shigeyoshi¹,Fujikura Yoshiaki¹,Ito Susumu¹

Affiliation:

1. Tochigi Research Laboratories of Kao Corporation, 2606 Akabane, Ichikai, Haga, Tochigi 321-34, and Wakayama Research Laboratories of Kao Corporation, 1334 Minato, Wakayama 640, 2 Japan

Abstract

A bacterial strain, designated KSM-7358, that can use α-cedrene for growth was isolated. The strain was identified as a member of the genus Rhodococcus and catalyzed the novel allylic oxidation of α-cedrene regiospecifically to produce ( R )-10-hydroxycedrene ( sec -cedrenol) with a very high yield. α-Curcumene was also produced as a possible metabolite of sec -cedrenol. A possible pathway for the microbial conversion of α-cedrene to sec -cedrenol and α-curcumene is proposed.

Publisher

American Society for Microbiology

Subject

Ecology,Applied Microbiology and Biotechnology,Food Science,Biotechnology

Link

https://journals.asm.org/doi/pdf/10.1128/aem.59.5.1336-1341.1993

Reference26 articles.

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