Author:
EL Makhloufy Smail,Tridane Malika,Majdi El Mehdi,Marouani Hamza,Zerraf Soufiane,Belhabra Mustafa,Cherqaoui Abdelouahed,Belaaouad Said
Abstract
A new cyclotriphosphate tetrahydrate of manganese and distrontium, MnSr2(P3O9)2.4H2O, was obtained as a polycrystalline sample by the method of ion-exchange resin. The cyclotriphosphate studied in this work is the second one having the formula MnSr2(P3O9)2.4H2O after BaZn2(P3O9)2.10H2O. Its crystallographic characterization, infrared studies and thermal behavior are given. The studied phosphate crystallizes in the triclinic system, P-1, with the following unit cell parameters : a = 6,653(1)Å, b = 7,110(1)Å, c = 5,123(1)Å, a = 103,37(2)°, b = 95,81(2)°, g = 93,04(2)° and Z = 1. The intermediate products of dehydration of MnSr2(P3O9)2.4H2O are MnSr2(P3O9)2.2H2O, mixture of ([Mn(PO3)2]∞ + 2g [Sr(PO3)2]∞) and mixture of ([Mn(PO3)2]∞ + 2b[Sr(PO3)2]∞). The thermal behavior of the studied condensed phosphate has been investigated and interpreted by IR absorption and X-ray diffraction experiments. The title compound can be used as catalyst, ion exchanger, the reactant in ionic conditions, intercalation reactions, superphosphate fertilizer and as an inorganic pigment in ceramics.
Publisher
Mediterranean Journal of Chemistry
Cited by
13 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Rhyolite as a Naturally Sustainable Thermoluminescence Material for Dose Assessment Applications;Sustainability;2022-06-06
2. Chemical preparation, crystallographic characterization, vibrational study and thermal behavior of a new cyclotriphosphate CaNH4P3O9 · H2O;Phosphorus, Sulfur, and Silicon and the Related Elements;2022-05-03
3. Synthesis, crystal structure, IR, Raman spectroscopy, and DFT computation of metacarboxyphenyl ammonium dihydrogenomonophosphate (C7H4NH3OOH) H2PO4(m-C AMP);INORG NANO-MET CHEM;2022
4. Physico-chemical characterization of natural rocks and their valorization on the removal of arsenic from aqueous solution;Materials Today: Proceedings;2022
5. Investigation of competitive adsorption and desorption of heavy metals from aqueous solution using raw rock: Characterization kinetic, isotherm, and thermodynamic;Materials Today: Proceedings;2021-12