Characterization and Selection of Materials for Air Biofiltration in Fluidized Beds

Abstract

A methodology is described for the selection of the best material to employ in a fluidized biofilter applied to volatil organic compounds (VOC) treatment. Two different supports were considered: one natural, scrap wood, and one synthetic, polyurethane foam. In a first part, the main objective was to establish the fluidizability of the selected solids. Particles of increasing moisture content were tested in rigs equipped with different air distribution technologies. Maps of flow regimes were drawn by varying air velocity and bed height. In the second part, the sorption capacities of the selected materials were evaluated at different humidity levels for a soluble organic compound (ethanol) and an insoluble one (toluene). Their ability for supporting viable microorganisms was then measured. Fine particles with 45% moisture content fluidized with the tuyere distributor in channeling and slugging regimes, whereas the conical distributor generated a spouted bed regime. Coarse wood particles with 45% moisture commonly used in fixed bed biofilters were considered as less suitable due to limitations borne by their fluidization regimes. Finally polyurethane foam filled with Agar gel could not endure the mechanical stress to which particles are subjected in fluidized beds. It was shown that a 45% moisture content was optimum to ensure transfer for both soluble and hydrophobic compounds. Considering the biological criterion, it appeared that a 45% humidity level was sufficient to ensure biomass growth and biodegradation of pollutants on fine scrap wood particles.