Copolymers for electronic, optical, and sensing applications with engineered physical properties

Abstract

Electronic and optoelectronic devices often require multifunctional properties combined with conductivity that are not achieved from a single species of molecules. The capability to tune chain length, shape, and physicochemical characteristics of conductive copolymers provides substantial benefits for a wide range of scientific areas that require unique and engineered optical, electrical, or optoelectronic properties. Although efforts have been made to develop synthetic routes to realize such promising copolymers, an understanding of the process–structure–property relationship of the synthesis methods needs to be further enhanced. In addition, since traditional methods are often limited to achieving pinhole-free, large-area coverage, and conformal coating of copolymer films with thickness controllability, unconventional synthetic strategies to address these issues need to be established. This Perspective article intends to enhance knowledge on the process–structure–property relationship of functional copolymers by providing the definition of copolymers, polymerization mechanisms, and a comparison of traditional and emerging synthetic methods with reaction parameters and tuned physical properties. In parallel, practical applications featuring the desired copolymers in electronic, optical, and sensing devices are showcased. Last, a pathway toward further advancement of unique copolymers for next-generation device applications is discussed.