Affiliation:
1. Theoretical Chemistry Laboratory, Unit of Theoretical and Structural Physical Chemistry, Namur Institute of Structured Matter, University of Namur 1 , B-5000 Namur, Belgium
2. School of Chemistry, University of East Anglia, Norwich Research Park 2 , Norwich NR4 7TJ, United Kingdom
Abstract
This work reports on the first computational quantum-chemistry implementation of the hyper-Rayleigh scattering optical activity (HRS-OA), a nonlinear chiroptical phenomenon. First, from the basics of the theory, which is based on quantum electrodynamics, and focusing on the electric dipole, magnetic-dipole, and electric-quadrupole interactions, the equations for the simulation of the differential scattering ratios of HRS-OA are re-derived. Then, for the first time, computations of HRS-OA quantities are presented and analyzed. They have been enacted on a prototypical chiral organic molecule (methyloxirane) at the time-dependent density functional theory level using a broad range of atomic orbital basis sets. In particular, (i) we analyze the basis set convergence, demonstrating that converged results require basis sets with both diffuse and polarization functions, (ii) we discuss the relative amplitudes of the five contributions to the differential scattering ratios, and (iii) we study the effects of origin-dependence and derived the expression of the tensor shifts and we prove the origin-independence of the theory for exact wavefunctions. Our computations show the ability of HRS-OA as a nonlinear chiroptical method, able to distinguish between the enantiomers of the same chiral molecule.
Funder
Fonds de la Recherche Scientifique-FNRS
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Reference83 articles.
1. Specification of molecular chirality;Angew. Chem., Int. Ed. Engl.,1966
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3 articles.
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