Affiliation:
1. School of Chemistry and Chemical Engineering, Nantong University , Nantong 226007, China
Abstract
In this paper, an island-like Re-containing phytate bimetal nanocluster catalyst was uniformly prepared on nickel foam by the chemical induced deposition@self-assembly method. The existence of valence-enriched Re and hydrophilic phytate molecules will improve the active area, charge transfer rate, and wetting ability of the intrinsic NiP catalyst. The bifunctional NiRe-IP6 catalyst can drive 100 mA/cm2 glucose oxidation reaction (GOR) and hydrogen evolution reaction (HER) processes by only 1.28 V [vs reversible hydrogen electrode (RHE)] and −0.115 V (vs RHE) in alkaline glucose electrolyte, respectively, outperforming almost all the as-reported GOR/HER bifunctional catalysts, especially at high current density.
Funder
National Natural Science Foundation of China
Jiangsu Specially-Appointed professor
Natural Science Foundation of Jiangsu Province
general project of natural science research in Jiangsu colleges and universities
Research Fund of Nantong University
national college students' innovation and entrepreneurship training program
Subject
Physics and Astronomy (miscellaneous)