The magnetic and magnetocaloric properties of Al-rich Al0.85+xSi0.15Fe2B2 compounds prepared by drop-casting

Author:

Stillwell Kyra1ORCID,Kramer Noah2,Birch Bryan1ORCID,Reese Brandon1,Pathak Arjun K.2ORCID,Khan Mahmud1ORCID

Affiliation:

1. Department of Physics, Miami University 1 , Oxford, Ohio 45056, USA

2. Department of Physics 2 , SUNY Buffalo State, Buffalo, New York 14222, USA

Abstract

Owing to the relative abundance of its constituent elements and large magnetocaloric properties observed near room temperature, the AlFe2B2 system has attracted much attention recently. Here, we have studied the magnetic and magnetocaloric properties of Al0.85+xSi0.15Fe2B2 (x = 0.2, 0.4) prepared by drop-casting followed by annealing and acid treatment. The second order ferromagnetic phase transitions were observed near room temperature (∼298–305 K) and peak magnetic entropy changes (−ΔSM) of more than −6 J kg−1 K−1 were observed for a field change of 5 T. The results are discussed in terms of the impurity phases formed in the compounds due to excess aluminum.

Funder

National Science Foundation

Office of Undergraduate Research, SUNY, Buffalo State

Publisher

AIP Publishing

Subject

General Physics and Astronomy

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