Low thermal conductivity in A-site high entropy perovskite relaxor ferroelectric

Author:

Xiong Wei12,Zhang Hangfeng2,Hu Zimeng2ORCID,Reece Michael J2,Yan Haixue2ORCID

Affiliation:

1. Light Alloy Research Institute, Central South University, Changsha 410083, China

2. School of Engineering and Materials Science, Queen Mary University of London, Mile End Road, London E1 4NS, United Kingdom

Abstract

An A-site disordered high entropy perovskite (Pb1/6Ba1/6Sr1/6Ca1/6Na1/6Bi1/6)TiO3 (PBSCNBi) ceramic was prepared by a solid-state reaction method. XRD and scanning electron microscopy-energy dispersive x ray confirmed a single-phase tetragonal solid solution. Dielectric and hysteresis loop measurements showed relaxor ferroelectricity at room temperature; Curie Weiss fitting gives a Burns temperature (Tb) of 123 °C, and Vogel–Fulcher fitting gives a freezing temperature (Tf) of −67.24 °C, which confirms the room-temperature relaxor ferroelectricity of PBSCNBi. This is attributed to local chemical inhomogeneities in the high entropy ceramics. PBSCNBi also has a low thermal conductivity (1.15 W m−1 K−1 at room temperature) compared to all of its constituent simple perovskites (e.g., BaTiO3, PbTiO3, SrTiO3 CaTiO3, and Na1/2Bi1/2TiO3 in the range of 25–100 °C), which is attributed to the enhanced phonon scattering by both polar nanoregions and the mass contrast effect in the multi-element perovskite. This work demonstrates the great potential of making A-site high entropy ceramics with relaxor ferroelectric properties.

Funder

China Scholarship Council

Publisher

AIP Publishing

Subject

Physics and Astronomy (miscellaneous)

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