The effect of grain boundaries and precipitates on the mechanical behavior of the refractory compositionally complex alloy NbMoCrTiAl

Abstract

Refractory compositionally complex alloys (CCAs) have been found to exhibit promising high-temperature properties. However, the brittleness of most CCAs at room temperature limits their application. To understand the influence of microstructure on the deformation behavior of these alloys, we conducted micromechanical experiments, including nanoindentation and micropillar compression tests, on a representative NbMoCrTiAl alloy at room temperature. The indentation at the grain boundaries showed increased shear stress and hardness compared to the matrix (ordered B2 crystal structure) due to the presence of local intermetallic precipitates (C14 and A15 phases). Although the NbMoCrTiAl alloy exhibits no ductility at the millimeter scale as shown in previous studies, the micropillars at the grain boundaries, which were decorated with precipitates, demonstrated higher yield strength and significant plastic strain >30% at room temperature. Numerous slip lines were observed, while cracks and fracture occurred at higher levels of deformation. The grain boundaries with precipitates increased the probability of crack initiation and propagation, but they did not necessarily lead to catastrophic failure of the pillars.