Impact of iso-structural template layer on stabilizing pyrochlore Bi2Rh2O7

Author:

Ohno M.1ORCID,Fujita T. C.1ORCID,Kawasaki M.12ORCID

Affiliation:

1. Department of Applied Physics and Quantum-Phase Electronics Center, University of Tokyo 1 , Tokyo 113-8656, Japan

2. RIKEN Center for Emergent Matter Science (CEMS) 2 , Wako 351-0198, Japan

Abstract

We present an epitaxial stabilization of pyrochlore Bi2Rh2O7 on the Y-stabilized ZrO2 (YSZ) (111) substrate by inserting a pyrochlore Eu2Ti2O7 template layer, otherwise Bi-based layered structures being formed directly on the YSZ (111) substrate. This result reveals that “iso-structural crystal phase” plays an important role in the interfacial phase control. The Bi2Rh2O7 film exhibits p-type electrical conduction with the lowest longitudinal resistivity (ρxx) among the reported Rh pyrochlore oxides. Such parameters as ρxx, carrier density, and mobility show almost no temperature dependence in the measured range of 2–300 K.

Funder

Japan Society for the Promotion of Science

Murata Science Foundation

Mizuho Foundation for the Promotion of Sciences

Iketani Science and Technology Foundation

Kazuchika Okura Memorial Foundation

Yazaki Memorial Foundation for Science and Technology

Mitsubishi Foundation

Publisher

AIP Publishing

Subject

Physics and Astronomy (miscellaneous)

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