Microscopic observation of two-level systems in a metallic glass model

Author:

Mocanu Felix C.1ORCID,Berthier Ludovic23ORCID,Ciarella Simone1ORCID,Khomenko Dmytro45ORCID,Reichman David R.4ORCID,Scalliet Camille6ORCID,Zamponi Francesco1ORCID

Affiliation:

1. Laboratoire de Physique de l’École Normale Supérieure, ENS, Université PSL, CNRS, Sorbonne Université, Université de Paris, 75005 Paris, France

2. Yusuf Hamied Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, United Kingdom

3. Laboratoire Charles Coulomb (L2C), Université de Montpellier, CNRS, 34095 Montpellier, France

4. Department of Chemistry, Columbia University, 3000 Broadway, New York, New York 10027, USA

5. Dipartimento di Fisica, Sapienza Università di Roma, P.le A. Moro 2, I-00185 Rome, Italy

6. DAMTP, Centre for Mathematical Sciences, University of Cambridge, Wilberforce Road, Cambridge CB3 0WA, United Kingdom

Abstract

The low-temperature quasi-universal behavior of amorphous solids has been attributed to the existence of spatially localized tunneling defects found in the low-energy regions of the potential energy landscape. Computational models of glasses can be studied to elucidate the microscopic nature of these defects. Recent simulation work has demonstrated the means of generating stable glassy configurations for models that mimic metallic glasses using the swap Monte Carlo algorithm. Building on these studies, we present an extensive exploration of the glassy metabasins of the potential energy landscape of a variant of the most widely used model of metallic glasses. We carefully identify tunneling defects and reveal their depletion with increased glass stability. The density of tunneling defects near the experimental glass transition temperature appears to be in good agreement with experimental measurements.

Funder

European Research Council

Simons Foundation

Agence Nationale de la Recherche

Publisher

AIP Publishing

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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