Affiliation:
1. M.N. Mikheev Institute of Metal Physics of Ural Branch of Russian Academy of Sciences , Ekaterinburg 620990, Russia
Abstract
Solid solutions of ZryTi1−yS2 (y = 0.1, 0.2) compositions have been synthesized. The electrochemical introduction of lithium is carried out by the galvanostatic intermittent titration technique. An isothermal section of the phase diagram of the LixZryTi1−yS2 system at room temperature has been constructed. The limiting solubility of lithium in solid solutions decreases with an increasing amount of titanium substituted for zirconium. It was noted that at low lithium concentrations (x < 1), there is no change in the E(x) dependence when titanium is replaced by zirconium. This may indicate the formation of separate TiS2 and ZrS2 layers.
Funder
Ministry of Education and Science of the Russian Federation