Using a Au/pitted a-plane GaN substrate to aggregate polar molecules for highly efficient surface-enhanced Raman scattering

Abstract

Searching for efficient surface-enhanced Raman scattering (SERS) substrates remains a challenge. In this study, we used metal–organic chemical vapor deposition to directly grow a pitted a-plane GaN thin film, subsequently covered by a thin Au layer (∼25 nm), for use as a SERS substrate, without the need for any additional etching or lithography process. The SERS substrate containing these micrometer-sized pits provided a low limit of detection (∼10−9 M) for Rhodamine 6G (R6G), with a high enhancement factor (4.27 × 108) relative to normal Raman spectroscopy. Furthermore, Raman spectral mapping indicated that most of the R6G molecules were concentrated in the pits, enhancing the localization of the probe molecules for further analysis. The same molecular localization phenomenon was also effective for polar methylene blue but not for nonpolar paraffin. The molecular aggregation became more ambiguous upon increasing the thickness of the Au layer, suggesting that the polarity of the Ga and N atoms in the pits was responsible for the efficient aggregation of the polar R6G molecules, which could be potentially beneficial for biomedical detection.