Effect of charge diameter on detonation parameters in the mixture of gelled nitromethane/microballoons

Author:

Mochalova Valentina1ORCID,Utkin Alexander1ORCID,Shakula Mikhail12,Lavrov Vladimir1ORCID

Affiliation:

1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS 1 , Chernogolovka, Russia

2. MIPT 2 , Dolgoprudny, Russia

Abstract

In this work, the detonation wave structure and detonation parameters of mixtures of gelled nitromethane (NM) with hollow glass microballoons (GMBs) are investigated with a laser velocimetry technique. It is shown that the addition from 0.5 to 13 wt. % GMB with the mean diameter of 70 μm does not qualitatively change the reaction zone structure of gelled NM, and it corresponds to the Zeldovich–von Neumann–Döring theory, predicting the formation of the von Neumann spike. The detonation parameters of the explosive mixture monotonically decrease—in particular, the ideal detonation velocity drops from 6.3 km/s for gelled NM to 3.7 km/s for its mixture with 13 wt. % GMB. The addition of GMB leads to a significant reduction in the critical detonation diameter, which decreases from 16.5 mm in gelled NM to 3.5 mm in the mixture with 8 wt. % GMB. The influence of polymethylmethacrylate concentration in the mixture of gelled NM with GMB on the value of critical diameter of the mixture is observed.

Funder

Russian Foundation for Basic Research

Ministry of Science and Higher Education of the Russian Federation

Publisher

AIP Publishing

Subject

Condensed Matter Physics,Fluid Flow and Transfer Processes,Mechanics of Materials,Computational Mechanics,Mechanical Engineering

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