Sustainable thermoelectric materials: Utilizing Fukushima weathered biotite via molten salt treatment

Author:

Honda Mitsunori1ORCID,Kaneta Yui123ORCID,Muraguchi Masakazu4ORCID,Hayakawa Kosetsu14ORCID,Oda Masato5ORCID,Iino Chiaki5,Ishii Hiroyuki6ORCID,Goto Takuya7ORCID

Affiliation:

1. Materials Sciences Research Center (MSRC), Japan Atomic Energy Agency (JAEA) 1 , 2-4, Shirakata, Tokai-mura, Naka-gun, Tokai, Ibaraki 319-1195, Japan

2. Department of Chemical Science and Engineering, Graduate School of Science and Engineering 2 , , Kobe 657-8501, Japan

3. Kobe University 2 , , Kobe 657-8501, Japan

4. Faculty of Engineering, Hokkaido University of Science 3 , Sapporo, Hokkaido 006-8585, Japan

5. Department of Materials Science, Wakayama University 4 , Wakayama 640-8510, Japan

6. Department of Applied Physics, Faculty of Pure and Applied Sciences 5 , University of Tsukuba,1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573, Japan

7. Department of Science of Environment and Mathematical Modeling, Graduate School of Science and Engineering, Doshisha University 6 , Kyotanabe, Kyoto 610-0394, Japan

Abstract

This study examines the utilization of Fukushima weathered biotite (WB) as an alternative to conventional thermoelectric materials traditionally derived from rare and toxic substances. WB underwent milling, classification, and subsequent heat treatment via molten-salt treatment to produce crystals exhibiting conductivity akin to semiconductors within the 650–850 °C range. Evaluation of WB and the derived crystal’s electrical conductivity and Seebeck coefficient showcased their viability for high-temperature thermoelectric applications. Consequently, WB attained a dimensionless figure of merit (ZT) of 0.015, signaling its potential as a thermoelectric material that surpasses 650 °C.

Funder

Japan Society for the Promotion of Science

Publisher

AIP Publishing

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