The effect of O2 pressure on phase formation and superconductivity properties of Tl-based HTS

Author:

Surmanidze D. L.12,Lobzhanidze T. E.2,Metskhvarishvili I. R.13,Dgebuadze G. N.1,Gabunia V. M.14,Bendeliani B. G.1,Metskhvarishvili M. R.5,Jishiashvili D. A.67

Affiliation:

1. Ilia Vekua Sukhumi Institute of Physics and Technology, Laboratory of Cryogenic Technique and Technologies 1 , Tbilisi 0186, Georgia

2. Ivane Javakhishvili Tbilisi State University, Faculty of Exact and Natural Sciences, Department of Chemistry 2 , Tbilisi 0179, Georgia

3. Georgian Technical University, Faculty of Informatics and Control Systems, Department of Microprocessor and Measurement Systems 3 , Tbilisi 0175, Georgia

4. Petre Melikishvili Institute of Physical and Organic Chemistry of the Ivane Javakhishvili Tbilisi State University 5 , Tbilisi 0186, Georgia

5. “Talga” Institute of Georgian Technical University 4 , Tbilisi 0186, Georgia

6. V. Chavchanidze Institute of Cybernetics of the Georgian Technical University Tbilisi 6 , Tbilisi 0186, Georgia

7. Andronikashvili Institute of Physics of the Ivane Javakhishvili Tbilisi State University 7 , Tbilisi 0186, Georgia

Abstract

Thallium-based high-temperature superconductors exhibit excellent superconductivity performance (Tc, Jc). Formation of the Tl-based superconducting materials critically depends on the used precursor and synthesis conditions. In the present investigation, we used the in situ polymerization method for synthesizing high-purity and reaction-ability precursors. We find the critical dependence of Tl-based superconductor phase formation on the quantity of applied oxygen pressure. The experimental results showed that the Tl-1223 phase formed at an oxygen gas pressure at 1 to 2 atm, Tl-2223 phase at 3 atm, and Tl-2212 phase at 4 to 8 atm.

Publisher

AIP Publishing

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